The Origin of Atmospheric
Gases:
Major Gases:
Nitrogen
Nitrogen
in the atmosphere originated inside the early initial
formation of the Earth. It escaped into the atmosphere
primarily through volcanic eruptions. It takes part in
various biological reactions, but other than that, is largely
chemically inert (unreactive) except when heated to high
temperatures (several hundred degrees at least). Because
of that, it has accumulated to be the largest single component
- about 78% of the atmosphere.
Oxygen
The origin of oxygen in the atmosphere is primarily due to
photosynthesis. A very secondary source (and primary
source before the evolution of photosynthetic organisms) is
lightning strikes, which break water molecules at the surface
and in the atmosphere into its component hydrogen and oxygen.
Early in the Earth's history, there was almost no oxygen gas
in the atmosphere. When photosynthesis evolved more than
3 billion years ago, any oxygen that was released, immediately
combined with dissolved ionic iron in the ocean, to oxidize
that iron (basically, forming rust). This iron oxide
accumulated in vast layers around the world, known as "Banded
Iron Formations", or "BIF"s. These range in age
from more than 3 billion years old up to about 1.8 billion
years old, and are a major source of iron ore world wide (You
can see a beautiful example of a BIF in our museum in the
lobby of the X building on the SFC NW campus). And
oxygen was unable to increase in our atmosphere until
all that oceanic dissolved iron was oxidized. Thus
that also was a key control on the development of
multicellular life.
Oxygen is used up via respiration from animals
and bacterial decomposition, weathering of rocks at the
surface, and combustion mostly in forest fires.
Why does oxygen have the percentage it does in our
atmosphere? Imagine that it was much higher than it is.
The rate of combustion due to forest fires would increase,
lowering the percent of oxygen. Suppose that it was much
lower than it is today. The rate of
combustion due to forest fires would decrease,
and if O2 were low enough, even respiration would
decrease. This would cause the amount of oxygen to rise
again. So the amount of oxygen is self-regulating, and
it is unlikely that, since the accumulation of oxygen in the
atmosphere after the formation of BIFs, the percentage of
oxygen has been much more than a few percent higher or lower
than it is today, about 21%.
Argon
Argon
was present within the earth upon its original formation,
and is also formed by radioactive decay of 40K
into 40Ar. Argon is a
fairly heavy Noble Gas and is chemically unreactive, so
when it escapes from the earth through weathering or
volcanism, it simply stays in the Earth's
Atmosphere. Most of the Ar in our atmosphere today
is 40Ar,
suggesting that most of it was formed by radioactive
decay.
Interestingly, Argon is also a significant gas in the
atmospheres of Mars and Venus, and is mostly 40Ar, showing
us that Venus, Earth, and Mars share a similar
geochemistry.
Carbon Dioxide
Carbon dioxide is a common gas in the universe, and likely was
"primordial" (present from the original formation of the
Earth). It has gradually escaped from the Earth's
interior to be a major constituent of our early atmosphere.
There are many sources and sinks for CO2,
though. It continues to be added to the atmosphere from
the Earth's interior through volcanism. It is added also
through respiration from animals and from bacterial
decomposition of organic matter. Certain kinds of
weathering of rocks and minerals add it to the
atmosphere. And combustion of organic materials through
wild fires and human activities (power plants, heating,
automobiles) add it to the atmosphere. Underground
burning of abandoned coal mines also add significant amounts
to the atmosphere.
Carbon dioxide is removed from the atmosphere by
photosynthesis to form the "biosphere", and by absorption into
the oceans so much that there is about 60x more CO2
in the ocean than in the atmosphere. The formation of
fossil fuels has sequestered hundreds of times more CO2
than is presently in our atmosphere. In the ocean, it is
removed also by photosynthesis and even more importantly by
shelled organisms (molluscs, arthropods, corals, foraminifera,
echinoderms, and many others). So much has been
removed by shelled organisms during the history of our planet
that there is around 100,000x more CO2
in limestones worldwide than in the atmosphere. Without
those limestones, we would have FAR more CO2
in our atmosphere. (This is why the atmosphere of Venus
has around 100,000x more CO2 than our
atmosphere. No life ever evolved there.) Certain
weathering processes also remove as well as add CO2
from the atmosphere.
Minor (Trace) Gases:
Neon
Neon was present within the earth upon its original
formation. Neon is a Noble Gas and is chemically
unreactive, so when it escapes from the earth through
weathering or volcanism, it simply stays in the Earth's
Atmosphere.
Helium
Helium was present within the earth upon its
original formation. Helium is also formed from Alpha
Particle decay of many radioactive isotopes
withing the Earth. Helium is
a Noble Gas and is chemically unreactive, so it escapes
from the earth through weathering or volcanism, and winds
up in the Earth's Atmosphere.
Helium
is such a light atom that it continually escapes from the
Earth's atmosphere into space. It is, however, also
continually replenished via production from Alpha Particle
decay within the Earth, so we have a very small but likely
constant amount of He in the atmosphere.
Methane
Methane (CH4) gas is primarily produced by
anaerobic (without oxygen) respiration by bacteria, a process
called "methanogenesis". Its primary sources natural
sources are termites and oxygen-poor organic-rich soils
(wetlands) and marine sediments, although the soil and
sediment methane can be trapped for long periods.
Anthropogenic (production related to humans) CH4
is produced in rice paddy sediments and livestock, especially
ruminants, which have bacteria in their gut to help break down
cellulose. Humans themselves produce about 1 liter (1
quart) of CH4 per
day in our guts. Unfortunately, methane is also released
accidentally and sometimes deliberately during mining and
petroleum drilling operations (although the deliberate release
is now generally illegal).
Natural gas formed in soils and marine sediments may be
trapped by chemical reactions as solid materials known as clathrates
(methane hydrates). These are solids composed of water
molecules that trap CH4
molecules. They are stable only at low temperatures (in
permafrost) and high pressures (in deep sea sediments), and
there is concern that during periods of planetary warming,
large amounts can be released. This is thought to be the
reason for the Paleocene-Eocene
Thermal Maximum, a time of catastrophic short-term
temperature increases about 55 million years ago, which led to
world-wide extinctions.
Methane is the major component of Natural Gas, and is produced
primarily by heating of organic material under pressure.
Bacteria may also play a part as well.
Methane is removed from the atmosphere by a variety of
processes, most important of which is oxidation in the
Troposphere.
Krypton
Krypton was present withing the earth upon
its original formation. Krypton is a Noble Gas and
is chemically unreactive, so when it escapes from the
earth through weathering or volcanism, it simply stays in
the Earth's Atmosphere.
Hydrogen
Hydrogen is highly reactive and any H2
gas that is present in the atmosphere quickly combines with O2
to form water vapor. It is formed primarily through
lightning strikes that break water apart, so there is always a
very small amount in the atmosphere, although any given H2
molecule is not present very long.
Water
Water is a primordial component of the atmosphere, and
water vapor is added to the atmosphere whenever a volcano
erupts. There is evidence that there is still as much
water trapped in the Earth's crust and mantle as is present on
the surface of the Earth. Water is broken into its
component hydrogen and oxygen whenever lightning bolts
strike. The hydrogen can escape to space, so we can look
VERY long into the future to a time when the Earth may lose
its water.
Pollutant Gases:
Carbon Monoxide
Carbon monoxide [CO] (not to be confused with carbon
dioxide [CO2] is produced by incomplete combustion
of organic materials, principally hydrocarbons.
Why doesn't CO2 form
instead of CO? Either because there isn't enough time
during the burning process for oxygen to completely react with
the carbon in the hydrocarbon molecules, or because there
simply is not enough oxygen present during the burning
process.
This occurs in power plants, kerosene heaters, and especially
internal combustion engines. This
is why, among other things, it is important to keep your
car engine tuned up, and why you should never use a
kerosene heater indoors. Combustion without enough O2
produces CO instead of CO2.
As such, it is higher along roadways and downwind of major
coal-fired power plants.
Highly toxic and very dangerous.
Ammonia
The
volatilization of nitrogen fertilizers is believed to be the
most important anthropogenic source. However,
atmospheric ammonia from urban areas has been attributed to
vehicles (heating in internal combustion engines).
Nitrous Oxides
There are a variety of oxides of nitrogen in the
atmosphere, including N2O
(Nitrous Oxide, AKA Laughing Gas) and NO2.
Most of the nitrous oxides emitted into the atmosphere, from
natural and anthropogenic sources, is produced by microorganisms
such as bacteria and fungi
in soils and oceans. Soils under natural
vegetation are an important source of nitrous oxide, accounting
for 60% of all naturally produced emissions. Other natural
sources include the oceans (35%) and atmospheric chemical
reactions (5%). A 2019 study showed that
emissions from thawing permafrost are 12 times higher than
previously assumed. (from
Wiki).
Produced artificially in internal combustion engines and power
plants by reaction of N2 at high temperatures with
oxygen gas.
Sulfur Dioxide
Sulfur dioxide (SO2) is emitted naturally by
volcanoes. However,
about
99% of the sulfur dioxide in air comes from human sources.
The main source of sulfur dioxide in the air is industrial
activity that processes materials that contain sulfur, e.g. the
generation of electricity from coal, oil or gas that contains
sulfur. In addition, industrial activities that burn
fossil fuels containing sulfur can be important sources of
sulfur dioxide.
Some mineral ores also contain sulfur, and sulfur dioxide is
released when they are processed.
Sulfur dioxide is also present in motor vehicle
emissions, as the result of fuel combustion. In the past,
motor vehicle exhaust was an important, but not the main,
source of sulfur dioxide in air. However, this is no longer
the case.
ChloroFluoroCarbons
ChloroFluoroCarbons [CFCs] are a completely artificial
class of chemical compounds used as refrigerants and
propellants. In that role, they are very effective.
They are non-toxic, stable, and have good thermodynamic
properties. They are not currently being
manufactured. They break down slowly due to chemical
reactions in the atmosphere.